Biolage Smoothproof Shampoo & Conditioner Duo 2 x 400ml
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Delivery
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Matrix Biolage Smoothproof Shampoo & Conditioner Duo tames unruly hair for smoother, sleeker days.
This set includes 1 x Matrix Biolage Smoothproof Shampoo (400ml) and 1 x Matrix Biolage Smoothproof Conditioner (236ml), working together to gently cleanse, smooth, and control frizz. The shampoo creates a soft, creamy lather that lifts away daily buildup while helping hair lie flatter and more controlled.
The conditioner feels silky and light, coating each strand without heaviness and rinsing to a smooth, glossy finish. Hair feels softer to the touch, easier to brush, and less puffy in damp weather. This duo is ideal for frizzy, coarse, or hard-to-manage hair and is perfect for daily use or before heat styling, leaving hair looking more polished and feeling calmer all day.
How To Use Matrix Biolage Smoothproof Shampoo & Conditioner Duo
- Shampoo: Apply to wet hair and massage gently into scalp.
- Work into a rich lather from roots to ends.
- Rinse thoroughly and repeat if hair has heavy buildup.
- Conditioner: Squeeze out excess water after shampooing.
- Apply conditioner mainly to mid-lengths and ends.
- Comb through with fingers and leave for 1–3 minutes.
- Rinse well until hair feels silky but not coated.
- Use daily or whenever hair feels frizzy or hard to manage.
Matrix Biolage Smoothproof Shampoo & Conditioner Duo Ingredients
Matrix Biolage Smoothproof Shampoo: Aqua / Water / Eau, Sodium Laureth Sulfate, Coco-Betaine, Sodium Lauryl Sulfate, Glycol Distearate, Dimethicone, Sodium Chloride, Parfum / Fragrance, Sodium Hydroxide, Cocamide MIPA, Carbomer, Sodium Benzoate, Salicylic Acid, Hexyl Cinnamal, Limonene, Linalool, Camellia Sinensis Leaf Extract, Fumaric Acid, Mentha Piperita (Peppermint) Extract, Aloe Barbadensis Leaf Juice Powder, Propylene Glycol, Lecithin, Citric Acid.
Matrix Biolage Smoothproof Conditioner: Aqua / Water / Eau, Cetearyl Alcohol, Behentrimonium Chloride, Cetyl Esters, Isopropyl Alcohol, Parfum / Fragrance, Phenoxyethanol, Lactic Acid, Amodimethicone, Trideceth-6, Chlorhexidine Dihydrochloride, Hexyl Cinnamal, Limonene, Linalool, Camellia Sinensis Leaf Extract, Mentha Piperita (Peppermint) Extract, Aloe Barbadensis Leaf Juice Powder, Propylene Glycol, Lecithin, Citric Acid.
Note: Please refer to bottle for full ingredients.
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Sodium Laureth Sulfate Cleansers / surfactantsCleanser
Helps cleanse the hair and scalp by removing oil, sweat and product build-up.
May suitOily scalps, heavy product users and people who like a strong cleanse.
Worth knowingMay feel too cleansing for some dry, curly, colour-treated or sensitive hair types. This depends on the full formula and your hair needs.
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Coco-Betaine Cleansers / surfactantsMild surfactant
A mild, coconut-derived surfactant that helps cleanse and create a soft lather.
May suitPeople looking for gentle cleansing that doesn't feel stripping.
Worth knowingIt is often used alongside other surfactants to improve foam quality and overall mildness. Common in shampoos designed for frequent use.
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Sodium Lauryl Sulfate Cleansers / surfactantsCleanser
A cleansing surfactant that removes oil and build-up from the hair and scalp.
May suitOily scalps and routines that need a strong, clarifying wash.
Worth knowingCan be more cleansing than gentler surfactants. Many people use it happily, while others prefer milder options for everyday washing.
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Glycol Distearate Thickeners and stabilisersOpacifier and pearlising agent
Adds a pearlescent look and helps thicken and stabilise shampoos and conditioners.
May suitThose who like creamy, luxurious-feeling shampoo or conditioner textures.
Worth knowingIt also provides a mild conditioning feel, helping formulas spread smoothly through the hair. Its use is common in many everyday cleansing products.
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Dimethicone SiliconesSlip and shine agent
Smooths the hair surface, adds slip and shine and helps reduce frizz.
May suitFrizz-prone, coarse or dry hair wanting a smooth, glossy finish.
Worth knowingSome people prefer silicone-free formulas, especially for certain curl routines. It is widely used and helpful in many smoothing products.
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Sodium Chloride Thickeners and stabilisersViscosity adjuster
Sodium Chloride is used to adjust the thickness of shampoos and other cleansing formulas.
May suitThose interested in how a product’s texture and lather are achieved.
Worth knowingIt is a simple mineral salt that helps create a familiar shampoo feel and can influence how a cleanser spreads through the hair.
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Sodium Hydroxide pH adjusterspH adjuster
Helps control and stabilise the pH of haircare formulations.
May suitThose interested in how product pH affects scalp comfort or hair cuticle behaviour.
Worth knowingIt is used in very small amounts to bring a formula to the desired pH range. Once adjusted, it does not act as a strong alkaline agent in the finished product.
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Cocamide MIPA Cleansers / surfactantsFoaming surfactant
A coconut-derived surfactant that helps boost foam and improve the cleansing performance of shampoos.
May suitPeople who like a rich, stable lather in their cleansing products.
Worth knowingIt is often used alongside primary surfactants to enhance texture and mildness. Its viscosity‑boosting effect can also improve the feel of rinse‑off formulas.
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Carbomer Thickeners and stabilisersThickener and stabiliser
Carbomer helps thicken and stabilise gels, creams and styling formulas.
May suitAnyone who prefers smooth, consistent textures in styling or leave-in products.
Worth knowingIt helps formulas stay evenly mixed and glide easily through the hair or onto the scalp. It is widely used because it works in very small amounts and provides reliable texture.
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Sodium Benzoate PreservativesPreservative
Helps protect water-based products from spoilage so they stay usable.
May suitAll products that need a preservative system.
Worth knowingOften paired with other preservatives for broad protection.
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Salicylic Acid Exfoliating acidsScalp exfoliant
Helps dissolve dead skin buildup on the scalp and supports a clearer, fresher surface.
May suitPeople dealing with flaky scalps, congestion or product buildup.
Worth knowingIt is widely used in scalp-care formulas because it breaks down excess oils and debris without needing physical scrubbing. Often found in dandruff-control products.
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Hexyl Cinnamal Fragrance ingredientsFragrance component
A fragrance ingredient used to give products a light, floral scent.
May suitThose who enjoy subtly scented haircare products.
Worth knowingIt is one of the fragrance components that must be listed separately when present above certain levels. People with known fragrance sensitivities may choose to monitor for it.
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Limonene Fragrance ingredientsFragrance component
A fragrance component that also occurs naturally in many citrus and plant oils.
Worth knowingA fragrance component that must be listed separately on labels because a minority of people can be sensitive to it. Its presence is normal, required disclosure and is not a quality signal.
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Linalool Fragrance ingredientsFragrance component
A fragrance component found naturally in many flowers and spices.
Worth knowingA fragrance component that must be listed separately on labels because a minority of people can be sensitive to it. Its presence is normal, required disclosure and is not a quality signal.
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Camellia Sinensis Leaf Extract Botanical extractsBotanical antioxidant extract
A plant extract rich in antioxidants that can help support scalp and hair comfort.
May suitThose interested in soothing or antioxidant-rich botanical ingredients.
Worth knowingIt is commonly used in haircare for its calming and conditioning properties. Its gentle nature makes it suitable for a wide range of formulations.
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Fumaric Acid pH adjusterspH adjuster
Helps regulate and maintain the pH level of haircare formulations.
May suitThose interested in well‑balanced, stable formulations that perform consistently.
Worth knowingIt is a commonly used organic acid that supports formula stability and product feel. Its inclusion helps ensure other ingredients work as intended.
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Aloe Barbadensis Leaf Juice Powder Botanical extractsSoothing botanical extract
A powdered form of aloe that helps hydrate and soothe the hair and scalp.
May suitThose looking for gentle hydration or scalp comfort.
Worth knowingAloe extracts are widely used in haircare for their lightweight conditioning and calming feel. The powdered form is simply a concentrated version that is rehydrated during formulation.
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Propylene Glycol HumectantsHumectant
Helps hold moisture and carry other ingredients through the formula.
May suitMost hair types as part of a moisturising formula.
Worth knowingA widely used humectant and carrier ingredient.
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Lecithin Conditioning agentsEmollient & conditioning agent
Lecithin helps soften and condition the hair while supporting product texture.
May suitThose seeking added softness, moisture support or smoother-feeling hair.
Worth knowingIt is a phospholipid commonly derived from soy or sunflower and is valued for its ability to enhance spreadability and moisture retention. It can also help stabilise certain formulations.
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Citric Acid pH adjusterspH adjuster
Fine-tunes the product pH, which can help the hair surface feel smooth.
May suitMost hair types as part of a balanced formula.
Worth knowingUsually present in small amounts to balance the formula.
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Cetearyl Alcohol Conditioning agentsFatty alcohol conditioner
A fatty alcohol that helps soften hair and improve the texture of formulations.
May suitPeople looking for smoother, more manageable hair or richer, creamier product textures.
Worth knowingDespite the name, fatty alcohols are moisturising and conditioning rather than drying. They also help stabilise and thicken many haircare formulas.
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Behentrimonium Chloride Conditioning agentsConditioning agent
A conditioning agent that helps detangle and soften, reducing static and roughness.
May suitMost hair types, especially tangle-prone or coarse hair.
Worth knowingA common conditioner ingredient despite the chloride name, which simply describes its chemistry.
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Cetyl Esters Conditioning agentsEmollient / slip enhancer
Provides slip and softness while helping to smooth the hair’s surface.
May suitPeople looking for smoother, more manageable hair textures.
Worth knowingCetyl esters are wax‑like emollients that improve product spreadability and give a soft, conditioned feel. They are commonly used to enhance texture without heaviness.
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Isopropyl Alcohol SolventsSolvent
Helps dissolve ingredients and supports quick-drying formulas.
May suitThose using styling products that benefit from fast evaporation, such as sprays.
Worth knowingIt is commonly used at low levels to improve texture and spreadability. It evaporates quickly, leaving minimal residue on the hair.
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Phenoxyethanol PreservativesPreservative
Helps keep the product stable and pleasant to use after opening.
May suitAll products that need protecting from spoilage.
Worth knowingA very common, well-studied preservative used at low levels.
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Lactic Acid pH adjusterspH adjuster
Helps adjust and maintain the product’s pH for optimal performance.
May suitThose looking for formulas that help smooth the cuticle or gently refine the scalp surface.
Worth knowingLactic Acid can also provide mild hydrating and smoothing benefits in haircare. Its pH-balancing role helps support product stability and performance.
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Amodimethicone SiliconesConditioning silicone
A conditioning silicone that targets rougher areas of the hair to smooth and protect.
May suitDamaged, frizz-prone or colour-treated hair wanting targeted smoothing.
Worth knowingDesigned to deposit where hair needs it most. Some prefer silicone-free formulas by choice.
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Trideceth-6 Cleansers / surfactantsSolubiliser / surfactant
A non-ionic surfactant that helps blend oil-soluble ingredients into water-based formulas.
May suitThose using products with oils or silicones who want them to rinse evenly without residue.
Worth knowingIt is commonly used in shampoos and styling products to support stable, uniform textures. Its mild nature makes it suitable for a wide range of formulations.
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Chlorhexidine Dihydrochloride PreservativesAntimicrobial preservative
Helps control microbial growth and maintain product freshness.
May suitThose interested in formulas designed to support a cleaner-feeling scalp environment.
Worth knowingIt is a well‑established antimicrobial ingredient sometimes used in scalp‑focused products. Its inclusion helps ensure product stability over time.
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Hexyl Cinnamal Fragrance ingredientsFragrance component
A fragrance ingredient used to give products a light, floral scent.
May suitThose who enjoy subtly scented haircare products.
Worth knowingIt is one of the fragrance components that must be listed separately when present above certain levels. People with known fragrance sensitivities may choose to monitor for it.
-
Limonene Fragrance ingredientsFragrance component
A fragrance component that also occurs naturally in many citrus and plant oils.
Worth knowingA fragrance component that must be listed separately on labels because a minority of people can be sensitive to it. Its presence is normal, required disclosure and is not a quality signal.
-
Linalool Fragrance ingredientsFragrance component
A fragrance component found naturally in many flowers and spices.
Worth knowingA fragrance component that must be listed separately on labels because a minority of people can be sensitive to it. Its presence is normal, required disclosure and is not a quality signal.
-
Camellia Sinensis Leaf Extract Botanical extractsBotanical antioxidant extract
A plant extract rich in antioxidants that can help support scalp and hair comfort.
May suitThose interested in soothing or antioxidant-rich botanical ingredients.
Worth knowingIt is commonly used in haircare for its calming and conditioning properties. Its gentle nature makes it suitable for a wide range of formulations.
-
Aloe Barbadensis Leaf Juice Powder Botanical extractsSoothing botanical extract
A powdered form of aloe that helps hydrate and soothe the hair and scalp.
May suitThose looking for gentle hydration or scalp comfort.
Worth knowingAloe extracts are widely used in haircare for their lightweight conditioning and calming feel. The powdered form is simply a concentrated version that is rehydrated during formulation.
-
Propylene Glycol HumectantsHumectant
Helps hold moisture and carry other ingredients through the formula.
May suitMost hair types as part of a moisturising formula.
Worth knowingA widely used humectant and carrier ingredient.
-
Lecithin Conditioning agentsEmollient & conditioning agent
Lecithin helps soften and condition the hair while supporting product texture.
May suitThose seeking added softness, moisture support or smoother-feeling hair.
Worth knowingIt is a phospholipid commonly derived from soy or sunflower and is valued for its ability to enhance spreadability and moisture retention. It can also help stabilise certain formulations.
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Citric Acid pH adjusterspH adjuster
Fine-tunes the product pH, which can help the hair surface feel smooth.
May suitMost hair types as part of a balanced formula.
Worth knowingUsually present in small amounts to balance the formula.